Here is a weird one. I decided to scrap the last image and do a fresh install.
I hooked up Wifi on the off start and got Samba share to work though it straight away. So I assume Samba must just config itself to the first live connection and no other after that.
When I tried to copy a psx image over Wifi I got the error messages in the uploaded jpg file that I took with my camera.
I rebooted the Pi, did the same thing and the error occurred again on my Pi3.
Can anyone make sense of the error please?
I just connected ethernet and to my surprise Samba is working on that. I was able to copy over images without an issue.